标题 |
Site-selective Eu3+ luminescence in Sr2ScLi(B2O5)2
Sr2ScLi(B2O5)2中Eu3+的位点选择性发光
相关领域
化学
硼
发光
分析化学(期刊)
放射化学
色谱法
光电子学
物理
有机化学
|
网址 | |
DOI | |
其它 | New pyroborate Sr2ScLi(B2O5)2 (SSLBO) doped with Eu3+ has been synthesized for the first time by the conventional solid-state method and investigated by spectroscopic means. At 300 K the material exhibits strong orange-red luminescence with a maximum at 613.5 nm. At 5 K the spectra of Eu3+ at different Sr sites can be distinguished by using different excitation wavelengths – 395 nm and 405 nm. The O2+–Eu3+ charge transfer transition in the absorption spectrum has a maximum at 260 nm and 245 nm for 2% and 0.1% Eu3+, respectively. The luminescence radiative decay time of Eu3+ at Sc, Sr(1) and Sr(2) sites is 4.6 ms, 1.4 ms and 2.6 ms, respectively. The energy transfer resulting from dipole–dipole interactions has been analyzed using the Inokuti–Hirayama model and R0 is calculated to be 12.7 ± 1.6 Å. |
求助人 | |
下载 | 该求助完结已超 24 小时,文件已从服务器自动删除,无法下载。 |
温馨提示:该文献已被科研通 学术中心 收录,前往查看
科研通『学术中心』是文献索引库,收集文献的基本信息(如标题、摘要、期刊、作者、被引量等),不提供下载功能。如需下载文献全文,请通过文献求助获取。
|