标题 |
Hydrometallurgical investigation routed through microwave (MW) assisted leaching and solvent extraction using ionic liquids for extraction and recovery of molybdenum from spent desulphurization catalyst
微波辅助浸出——离子液体溶剂萃取法从废脱硫催化剂中提取和回收钼的湿法冶金研究
相关领域
浸出(土壤学)
钼
离子液体
化学
双水相体系
催化作用
萃取(化学)
水溶液
金属
溶剂
水溶液中的金属离子
无机化学
核化学
色谱法
有机化学
土壤水分
土壤科学
环境科学
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其它 | abstract:The integrated hydrometallurgical approach routed through Microwave (MW) assisted leaching-cum-solvent extraction-precipitation for recovery of MoO3 from spent desulphurization catalyst was investigated. Selective separation of molybdenum (Mo) was obtained using the ionic liquid as Cyphos 104. In leaching study the role of MW power and H2SO4 concentration appears to be critical on transforming sulphide and oxide phase of metals (Mo, Al and Ni) in the spent catalyst phase into respective metal sulphate that led to have enhancement of metal leaching efficiency. At the optimum leaching condition: MW power of 1000Watt, 10(V/V)% H2SO4, 10(W/V)% (S/L) more than 99 % of Mo, 98 % of Al and 99 % of Ni was extracted with dilute acid. The leach liquor bearing 10.01 g/L of Mo, 27 g/L of Al and 2 g/L of Ni was subjected to Mo extraction using the ionic liquid(IL) of Cyphos 104. |
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