| 标题 |
 Enzymatic Synthesis of l-Carnitine by Reduction of an Achiral Precursor: the Problem of Reduced Nicotinamide Adenine Dinucleotide Recycling 非手性前体还原酶法合成l-肉碱：还原烟酰胺腺嘌呤二核苷酸再循环问题
相关领域
烟酰胺腺嘌呤二核苷酸
辅因子
化学
烟酰胺
NAD+激酶
生物化学
黄素腺嘌呤二核苷酸
酶
脱氢酶
烟酰胺腺嘌呤二核苷酸磷酸
烟酰胺
氧化还原
有机化学
氧化酶试验
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| 网址 | |
| DOI | |
| 其它 | Synthesis of l-carnitine has been carried out by the enzymatic reduction of the carbonyl group of the achiral precursor 3-dehydrocarnitine with the oxidized nicotinamide adenine dinucleotide-linked carnitine dehydrogenase. Various enzymatic or chemical systems have been tested to regenerate the reduced nicotinamide adenine dinucleotide oxidized in the reduction of 3-dehydrocarnitine. Because of the instability of this compound in aqueous solutions, it was added by continuous feeding as a rate-limiting constituent in the reaction mixture. Under these conditions, conversion yields of 95% were achieved with the glucose plus glucose dehydrogenase system. |
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