| 标题 |
 Single-crystal field-effect transistors based on a fused-ring electron acceptor with high ambipolar mobilities 基于高双极迁移率熔融环电子受体的单晶场效应晶体管
相关领域
双极扩散
材料科学
戒指（化学）
接受者
电子
电子受体
Crystal（编程语言）
动性
晶体管
光电子学
有机半导体
单晶
场效应晶体管
电子迁移率
化学物理
结晶学
光化学
凝聚态物理
化学
电气工程
物理
有机化学
社会学
工程类
电压
程序设计语言
量子力学
计算机科学
社会科学
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Chengyi Xiao, Cheng Li, Feng Liu, Lei Zhang, Weiwei Li In this study, we successfully obtained the single crystal of a well-known fused-ring electron acceptor Y6 and realized high ambipolar charge transports in single-crystal organic field-effect transistors (SC-OFETs). These were achieved by growing the single crystal of Y6via a simple solvent evaporation method and then using a “gold trips sticking” technique. We found that in the single crystal structure Y6 exhibited two isomers with a chiral symmetry (M- or P-enantiomer), which were responsible for the two-dimensional porous networks. The hierarchical structures could be favorable for charge transport along π–π stacking directions, as confirmed by SC-OFETs: high ambipolar mobilities with a hole mobility of 0.84 cm2 V−1 s−1 and an electron mobility of 1.94 cm2 V−1 s−1 were obtained. This could be further used as phototransistors with a high responsivity of 1.2 × 103 A W−1 and a photosensitivity of 2.1 × 104. |
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