假电容
材料科学
超级电容器
储能
电容
电解质
纳米技术
化学工程
电极
量子力学
物理
工程类
物理化学
功率(物理)
化学
作者
Bhanu Ranjan,Davinder Kaur
出处
期刊:Small
[Wiley]
日期:2023-12-15
被引量:11
标识
DOI:10.1002/smll.202307723
摘要
Abstract Exploiting pseudocapacitance in rationally engineered nanomaterials offers greater energy storage capacities at faster rates. The present research reports a high‐performance Molybdenum Oxynitride (MoON) nanostructured material deposited directly over stainless‐steel mesh (SSM) via reactive magnetron sputtering technique for flexible symmetric supercapacitor (FSSC) application. The MoON/SSM flexible electrode manifests remarkable Na + ‐ion pseudocapacitive kinetics, delivering exceptional ≈881.83 F g −1 capacitance, thanks to the synergistically coupled interfaces and junctions between nanostructures of Mo 2 N, MoO 2 , and MoO 3 co‐existing phases, resulting in enhanced specific surface area, increased electroactive sites, improved ionic and electronic conductivity. Employing 3D Bode plots, b ‐value, and Dunn's analysis, a comprehensive insight into the charge‐storage mechanism has been presented, revealing the superiority of surface‐controlled capacitive and pseudocapacitive kinetics. Utilizing PVA‐Na 2 SO 4 gel electrolyte, the assembled all‐solid‐state FSSC (MoON/SSM||MoON/SSM) exhibits impressive cell capacitance of 30.7 mF cm −2 (438.59 F g −1 ) at 0.125 mA cm −2 . Moreover, the FSSC device outputs a superior energy density of 4.26 µWh cm −2 (60.92 Wh kg −1 ) and high power density of 2.5 mW cm −2 (35.71 kW kg −1 ). The device manifests remarkable flexibility and excellent electrochemical cyclability of ≈91.94% over 10,000 continuous charge–discharge cycles. These intriguing pseudocapacitive performances combined with lightweight, cost‐effective, industry‐feasible, and environmentally sustainable attributes make the present MoON‐based FSSC a potential candidate for energy‐storage applications in flexible electronics.
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