材料科学
湿度
氧化铈
兴奋剂
铈
相对湿度
纳米纤维
静电纺丝
化学工程
钨
掺杂剂
氧化物
纳米技术
复合材料
光电子学
聚合物
冶金
工程类
物理
热力学
作者
Xinge Wang,Xukun Wang,Wei Wei,Haiqing Jiang,Xijuan Li,Guo Liu,Zhiqi Zhu,Bingsheng Li,Yanbin Sheng,Jinyuan Zhou,Erqing Xie,Zhenxing Zhang
标识
DOI:10.1016/j.snb.2023.134210
摘要
Serious interference of humidity limits the wide application of ethanol gas sensors. The transition metal tungsten (W) doped cerium dioxide (CeO2), possessing a hydrophobic nature and rich oxygen vacancies, will tackle the humidity issue. Herein, the pristine and W-doped CeO2 hollow nanofibers were successfully fabricated by electrospinning. Oxygen vacancy content increases first and then decreases with the doping tungsten, and the 1 mol% W-doped CeO2 sample presents the largest content. Further, the 1 mol% W-doped CeO2 sensor exhibits an excellent response of 10.2 to 100 ppm ethanol at 200° C, 3.5 times higher than the pure CeO2 sensor, good selectivity, repeatability, and long-term stability. In addition, the responses of the W-CeO2 sensors are almost humidity independent. The resistances in air and ethanol decrease gradually with the humidity increases, leading to the humidity-resistant response, mainly attributed to the hindered carrier migration by the type-I CeO2/WO3 heterojunction. These results indicate that the appropriate W-doped CeO2 is a potential humidity-resistant gas-sensing material for ethanol sensing.
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