Exploring adsorption dynamics of heavy metals onto varied commercial microplastic substrates: isothermal models and kinetics analysis

微塑料 吸附 弗伦德利希方程 朗缪尔 重金属 环境化学 动力学 等温过程 化学 化学工程 朗缪尔吸附模型 金属 热力学 有机化学 工程类 物理 量子力学
作者
Anda-Gabriela Tenea,Cristina Dinu,Paul Alexandru Rus,Ioana Alexandra Ionescu,Ștefania Gheorghe,Vasile Ion Iancu,Gabriela Geanina Vasile,Luoana Florentina Pascu,Florentina Laura Chiriac
出处
期刊:Heliyon [Elsevier BV]
卷期号:10 (15): e35364-e35364 被引量:6
标识
DOI:10.1016/j.heliyon.2024.e35364
摘要

The increasing presence of plastics in the environment has raised concerns about their potential impact, especially as carriers of heavy metals such as Cd, Ni, and Pb. However, the adsorption mechanism of heavy metals on microplastics remains poorly understood. In this study, we investigated the adsorption behavior of Cd, Ni, and Pb by polystyrene (PS) and polypropylene (PP) microplastics to better comprehend their interaction and potential environmental implications. Our results revealed that equilibrium adsorption of microplastics with different heavy metals was achieved within a 6-h contact time. The FTIR analysis findings, which suggest that physical interactions play a significant role in the adsorption of heavy metals onto microplastics, are further supported by the observed changes in surface morphology after adsorption. We explored the influence of solution pH, contact duration, and initial concentration on the adsorption capacity and found significant effects on the adsorption behavior. To model the adsorption process, we applied Langmuir and Freundlich adsorption isotherm models and observed that the Langmuir model better fit the experimental data. Furthermore, we compared the pseudo-first and pseudo-second-order kinetic models and found that the pseudo-second-order model provided a more accurate description of the adsorption kinetics. Notably, the adsorption percentages varied depending on the type of microplastic and experimental conditions. Overall, this study enhances our understanding of the adsorption mechanism of heavy metals on microplastics and provides valuable insights into their behavior in aquatic environments. These findings have implications for the development of effective strategies for mitigating pollution caused by microplastics and heavy metals in aquatic ecosystems.
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