皮克林乳液
流变学
纳米纤维
纤维素
微观结构
复合数
乳状液
化学工程
材料科学
粒子(生态学)
相(物质)
吸附
复合材料
化学
有机化学
工程类
海洋学
地质学
作者
Fang Fang,Zijing Tian,Lihua Huang,Yongjian Cai,Paul Van der Meeren,Jianhui Wang
标识
DOI:10.1016/j.ijbiomac.2024.135281
摘要
Particle concentrations (w) and oil content (Φ) are crucial factors influencing the gel stability of Pickering emulsions. To understand the stabilization mechanism comprehensively, we prepared emulsion gels stabilized by CNF/DMY composite particles at various w (0.5-1.5 wt%) and Φ (0.2-0.6, v/v). The microstructure revealed the adsorption of these particles at the oil-water interface, with excess particles forming a three-dimensional network structure in the continuous phase. Rheological studies showed that the network structure of Pickering emulsions was significantly influenced by w and Φ, resulting in improved emulsion gel strength that hindered the movement of oil droplets and oxygen in the continuous phase, thereby enhancing emulsion stability. Three scenarios for the critical strain (γ
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