色素敏化染料
化学
酞菁
能量转换效率
光化学
太阳能电池
电子转移
电子供体
醛
分子内力
电化学
光伏系统
傅里叶变换红外光谱
化学工程
有机化学
物理化学
电极
光电子学
材料科学
催化作用
工程类
生物
电解质
生态学
作者
Betül Karadoğan,İbrahim Erden
出处
期刊:Main Group Chemistry
[IOS Press]
日期:2023-02-17
卷期号:22 (3): 329-335
摘要
In order to obtain higher power conversion performance in dye-sensitized solar cells, phthalocyanine compounds (ZnPc-1 and ZnPc-2) containing electron donor methoxy groups and aldehyde groups as anchors were synthesized in this study. The photovoltaic and electrochemical properties of these compounds were studied and their applicability as photosensitizers in DSSCs was investigated. The photovoltaic cell efficiencies (PCE) of the devices were in the range of 0.43–0.76 % under simulated AM 1.5 solar irradiation of 100 mW/cm2. Considering the photovoltaic performance of the produced DSSC devices, the anchor group and the chelate effect, it was observed that the efficiency increased, respectively, ZnPc-1 < ZnPc-2. The highest PCE value of 0.76 % was obtained with asymmetric ZnPc-2 based DSSC under. It has been explained that methoxy groups are electron donors and contribute to intramolecular electron mobility and that better electron transfer with single aldehyde anchor increases cell efficiency. In addition, the increase in the number of methoxy groups with known donor properties on the molecule also contributed to the increase in cell efficiency by increasing electron transfer. All compounds synthesized were characterized using FTIR, UV-vis and MS spectroscopic data.
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