番茄红素
类胡萝卜素
化学
顺反异构
胡萝卜素
异构化
抗氧化剂
食品科学
立体化学
生物化学
催化作用
出处
期刊:Food Chemistry
[Elsevier BV]
日期:2023-03-22
卷期号:421: 135954-135954
被引量:20
标识
DOI:10.1016/j.foodchem.2023.135954
摘要
Although most carotenoids in fruits and vegetables exist as the all-E-isomers, several carotenoids accumulated in the skin exist as the Z-isomers. However, the differences in the skin-related biological activities of the all-E- and Z-isomers are largely unknown. This study investigated the effects of E/Z-isomer ratios of lycopene and β-carotene on their ultraviolet (UV)-light-shielding ability and skin-related biological activities (i.e., antioxidant, skin anti-aging, and skin-whitening activities). Z-Isomer-rich lycopene and β-carotene were prepared by thermal isomerization of their all-E-isomers, i.e., the total Z-isomer ratios of lycopene and β-carotene were 97.7 and 89.0%, respectively. The Z-isomers exhibited higher UV-A- and UV-B-shielding abilities and greater skin-related biological activities (e.g., anti-elastase activity, hyaluronic acid production-promoting effect, anti-melanin formation activity, and inhibitory activity for melanin precursor darkening) in several assays than the all-E-isomers. These findings may contribute to understanding the significance of carotenoid Z-isomers in the skin and developing food ingredients that promote skin health.
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