化学
三氟甲磺酸
硒化物
组分(热力学)
组合化学
氧化磷酸化
有机化学
硒
催化作用
生物化学
热力学
物理
作者
Yun‐Qian Zhang,You‐Qin Jiang,Yong‐Hao Wang,Cong Qi,Yong Ling,Yanan Zhang,Gong‐Qing Liu
标识
DOI:10.1021/acs.joc.3c00788
摘要
Three-component selenofunctionalization processes of olefins, diselenides and sulfonamides, water, alcohols, or acids utilizing 1-fluoropyridinium triflate (FP-OTf) as a reaction promoter are reported. Under the optimal conditions, a broad range of vicinally functionalized selenide derivatives was accessible with high yields and excellent functional group compatibilities. Mechanistic studies revealed that the FP-OTf played a key role in this selenofunctionalization process.
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