New construction of polypyrrole interphase layers to improve performance stability of NaTi2(PO4)3 anode for aqueous Na-ion batteries

阳极 聚吡咯 材料科学 化学工程 电解质 涂层 导电聚合物 水溶液 聚苯胺 电化学 聚合物 法拉第效率 聚合 电极 化学 纳米技术 有机化学 复合材料 工程类 物理化学
作者
Wenjun Wang,Jiangtao Wu,Chaoliu Zeng
出处
期刊:Solid State Ionics [Elsevier BV]
卷期号:397: 116259-116259 被引量:2
标识
DOI:10.1016/j.ssi.2023.116259
摘要

NaTi2(PO4)3 (NTP) as a promising anode material for aqueous sodium-ion batteries has attracted widespread attention. However, the NTP material commonly exhibits significant capacity fade, possibly mainly attributing to the change of the chemical stability of NTP in the aqueous electrolytes. Coating NTP with polypyrrole (PPY) conductive polymers is a promising strategy to solve this problem, but in situ synthesis of the PPY polymer in the presence of the NTP active materials seems not to be easy, reported by the previous work, owing to the inferior adhesion of the synthesized PPY to the NTP surface. Thereby, this work has attempted ex situ synthesis of PPY coatings on the carbon-coated NTP (NTP/C) anode surface in the presence of small amounts of carbon conductive additives and organic binders, and then it shows that synthesized conductive PPY interphase layer can readily adhere to the NTP surface with no visible phase separation through the electrochemical oxidation polymerization under certain potentials in the pyrrole (PY)-containing electrolytes. The corresponding optimized oxidation modification conditions of the anode can be obtained, and the evolution law of the anode interface with the content of the electrolyte additives, the oxidation potential and the oxidation time can be established. Thus, the as-synthesized optimal modified anodes, with the thickness of about 24 μm for the PPY coating, are observed to have fairly large charge/discharge capacity of 228.6 mAh·g−1, high coulombic efficiency (> 95%) and enhanced cycling stability. Furthermore, a schematic for the charge/discharge processes involving possible reaction pathways at the modified anodes with the PPY layers in Na2SO4 aqueous electrolytes has been proposed.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
克姑美完成签到 ,获得积分10
2秒前
pangao完成签到,获得积分10
2秒前
ysssbq完成签到,获得积分10
4秒前
5秒前
上好佳完成签到 ,获得积分10
5秒前
大模型应助Yeong采纳,获得10
6秒前
量子星尘发布了新的文献求助30
6秒前
7秒前
123完成签到,获得积分10
7秒前
谢陈完成签到 ,获得积分10
8秒前
lilili完成签到,获得积分10
9秒前
10秒前
xiaoying发布了新的文献求助10
10秒前
SciGPT应助Eric_Liuzy采纳,获得10
11秒前
liu完成签到 ,获得积分10
11秒前
qixiaoqi发布了新的文献求助10
12秒前
13秒前
A溶大美噶发布了新的文献求助10
13秒前
14秒前
14秒前
15秒前
16秒前
17秒前
kevin发布了新的文献求助10
17秒前
满意的初南完成签到 ,获得积分10
18秒前
橙橙橙发布了新的文献求助10
18秒前
万能图书馆应助EVEN采纳,获得10
18秒前
18秒前
Yeong发布了新的文献求助10
19秒前
范先生发布了新的文献求助10
20秒前
disciple完成签到,获得积分10
21秒前
沉默凌寒完成签到,获得积分10
21秒前
cc完成签到,获得积分10
21秒前
22秒前
糖豆完成签到,获得积分10
22秒前
smottom完成签到,获得积分0
23秒前
贰鸟完成签到,获得积分0
23秒前
23秒前
火山蜗牛发布了新的文献求助10
24秒前
腿毛没啦完成签到,获得积分10
24秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
Research on Disturbance Rejection Control Algorithm for Aerial Operation Robots 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038569
求助须知:如何正确求助?哪些是违规求助? 3576279
关于积分的说明 11374944
捐赠科研通 3305979
什么是DOI,文献DOI怎么找? 1819354
邀请新用户注册赠送积分活动 892698
科研通“疑难数据库(出版商)”最低求助积分说明 815048