Nanocelluloses: A New Family of Nature‐Based Materials

Angewandte Chemie International EditionVolume 50, Issue 24 p. 5438-5466 Review Nanocelluloses: A New Family of Nature-Based Materials Prof. Dr. Dieter Klemm, Corresponding Author Prof. Dr. Dieter Klemm [email protected] Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Dieter Klemm, Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Tom Lindström, Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Derek Gray, Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this authorDr. Friederike Kramer, Dr. Friederike Kramer Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.deSearch for more papers by this authorSebastian Moritz, Sebastian Moritz Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.deSearch for more papers by this authorProf. Tom Lindström, Corresponding Author Prof. Tom Lindström [email protected] Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Dieter Klemm, Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Tom Lindström, Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Derek Gray, Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this authorMikael Ankerfors, Mikael Ankerfors Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.comSearch for more papers by this authorProf. Derek Gray, Corresponding Author Prof. Derek Gray [email protected] Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.ca Dieter Klemm, Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Tom Lindström, Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Derek Gray, Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this authorDr. Annie Dorris, Dr. Annie Dorris Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this author Prof. Dr. Dieter Klemm, Corresponding Author Prof. Dr. Dieter Klemm [email protected] Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Dieter Klemm, Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Tom Lindström, Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Derek Gray, Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this authorDr. Friederike Kramer, Dr. Friederike Kramer Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.deSearch for more papers by this authorSebastian Moritz, Sebastian Moritz Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.deSearch for more papers by this authorProf. Tom Lindström, Corresponding Author Prof. Tom Lindström [email protected] Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Dieter Klemm, Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Tom Lindström, Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Derek Gray, Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this authorMikael Ankerfors, Mikael Ankerfors Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.comSearch for more papers by this authorProf. Derek Gray, Corresponding Author Prof. Derek Gray [email protected] Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.ca Dieter Klemm, Polymet Jena Association and Jenpolymer Materials Ltd. & Co. KG, Wildenbruchstrasse 15, 07745 Jena (Germany), Fax: (+49) 3641-548-289 http://www.jenpolymer-materials.de Tom Lindström, Material Processes, Innventia AB, Box 5604, 11486 Stockholm (Sweden), Fax: (+46) 8-411-5518 http://www.innventia.com Derek Gray, Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this authorDr. Annie Dorris, Dr. Annie Dorris Department of Chemistry, McGill University, Pulp and Paper Building, 3420 University Street, Montreal, QC H3A 2A7 (Canada), Fax: (+1) 514-398-8254 http://www.mcgill.caSearch for more papers by this author First published: 20 May 2011 https://doi.org/10.1002/anie.201001273Citations: 3,235Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Cellulose goes nano: Renewed research effort on cellulose has led to nanoscale materials derived from this abundant, renewable, and potentially carbon-neutral source. Microfibrillated cellulose, nanocrystalline cellulose (see polarized microscopy image), and bacterial nanocellulose provide unique product opportunities: gels and foams, structured films of cellulose, and medical implants, respectively. Abstract Cellulose fibrils with widths in the nanometer range are nature-based materials with unique and potentially useful features. Most importantly, these novel nanocelluloses open up the strongly expanding fields of sustainable materials and nanocomposites, as well as medical and life-science devices, to the natural polymer cellulose. The nanodimensions of the structural elements result in a high surface area and hence the powerful interaction of these celluloses with surrounding species, such as water, organic and polymeric compounds, nanoparticles, and living cells. This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants. References 1 1aM. Pääkkö, M. Ankerfors, H. Kosonen, A. Nykänen, S. Ahola, M. Österberg, J. Ruokolainen, J. Laine, P. T. Larsson, O. Ikkala, T. Lindström, Biomacromolecules 2007, 8, 1934– 1941; 1bA. F. Turbak, F. W. Snyder, K. R. Sandberg, J. Appl. Polym. Sci. Appl. Polym. Symp. 1983, 37, 815– 827; 1cL. Wågberg, G. Decher, M. Norgren, T. Lindström, M. Ankerfors, K. Axnäs, Langmuir 2008, 24, 784– 795; 1dM. Henriksson, L. 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