蒽
化学
区域选择性
表面改性
反应性(心理学)
荧光
光化学
组合化学
催化作用
有机化学
物理化学
量子力学
医学
物理
病理
替代医学
作者
Dawei Tian,Guofei Shi,Mengmeng Fan,Xiaobing Guo,Yueqi Yuan,Sitian Wu,Jinyu Liu,Juanyi Zhang,Siyang Xing,Bolin Zhu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2021-10-19
卷期号:23 (21): 8163-8168
被引量:11
标识
DOI:10.1021/acs.orglett.1c02843
摘要
A novel 9,9a-BN anthracene 5 has been synthesized by the Ru-catalyzed electrocyclization of BN-aromatic enynes. The photophysical properties of 5 are different from those of all-carbon anthracene and other reported BN-anthracenes. The reactivity of 5 has been investigated by treating 5 with organolithium compounds, Br2, or N-iodosuccinimide. The resulting halogenated compounds can be easily functionalized via cross-coupling reactions. UV-vis and fluorescence spectroscopy of 5 have been investigated to explore the photophysical properties of these BN-anthracenes.
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