Rheological and tribological properties of low-temperature greases based on cellulose acetate butyrate gel

A new approach to produce biodegradable low-temperature greases, based on cellulose acetate butyrate (CAB) that dissolves in the medium of acetyl tributyl citrate (ATBC) at high temperatures and produces a gel during cooling because of phase separation, is proposed. Rheological properties of CAB solutions and gels in a wide temperature range from -80 °C to 160 °C were investigated with characterization of their viscoelasticity and viscoplasticity that arise because of the sol-gel transition of CAB/ATBC systems at 55 °C. CAB gelation reduces the wear coefficient tenfold when using ATBC as a lubricant but leads to a noticeable increase in the friction coefficient. To improve tribological properties of gel greases, additives of various solid particles were used: hexagonal boron nitride, graphite, and polytetrafluoroethylene (PTFE). The introduction of 10% to 30% additives in a gel grease containing 10% CAB has shown the preference of PTFE at a concentration of 10% for improving grease tribological characteristics.