分子印迹聚合物
化学
纳米复合材料
纳米材料
检出限
聚合物
电极
聚合
纳米技术
化学工程
安培法
电化学
色谱法
选择性
有机化学
材料科学
工程类
物理化学
催化作用
作者
Jinchun Hu,Zhenguo Zhang,Congcong Zhang,Jiancheng Zhang,Han Zhou,Fansheng Ning,Daijie Wang,Xin Du
出处
期刊:Talanta
[Elsevier]
日期:2022-06-01
卷期号:243: 123391-123391
被引量:2
标识
DOI:10.1016/j.talanta.2022.123391
摘要
Rare ginsenoside Rg3 is a main active ingredient in ginseng, which is more easily absorbed by human body and plays its role. Determination of Rg3 in edible and medicinal samples is a key factor for quality evaluation and effective monitoring of adulteration. In this study, an electrochemical sensor was developed based on molecularly imprinted polymer (MIP) and nanomaterial amplification. MIP was achieved by electro-polymerization with Rg3 as the template molecule and the functional monomer was o-phenylenediamine. Multi-walled carbon nanotubes (MWCNT) and titanium carbide (Ti3C2Tx) nanocomposites formed an excellent porous structure, which exhibited the advantages of increasing the specific surface area and electrical conductivity. The prepared sensor presented a great linear relation of Rg3 in the range of 10-2000 μg mL-1 with a limit of detection (LOD) of 0.34 μg mL-1. Importantly, the sensor was successfully utilized to detect ginsenoside Rg3 in different real samples.
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