异质结
材料科学
光催化
甲基橙
纳米颗粒
氧化还原
双金属片
化学工程
热液循环
纳米棒
纳米技术
降级(电信)
反应速率常数
原位
光电子学
金属
动力学
化学
催化作用
电子工程
物理
工程类
量子力学
有机化学
冶金
生物化学
作者
Wangwei Ren,Jingkai Yang,Wenjun Chen,Shouxin Zhang,Yu Sun,Yanzhi Zheng,Hongli Zhao,Bo Liang
标识
DOI:10.1016/j.materresbull.2022.111884
摘要
0D/2D SnO2/SnS2 S-scheme heterojunction with close contact interface was successfully constructed by in-situ growth of SnO2 nanoparticles on SnS2 nanosheets with a two-step hydrothermal method under electrostatic attraction. SnO2/SnS2 composite with molar ratio of 1:2 shows the excellent photocatalytic performance for the reduction of Cr(VI) (98.4% for 40 min) and the degradation of methyl orange (99.1% for 70 min) under visible light irradiation. The apparent rate constant for Cr(VI) reduction is about 66.7, 7.6, and 4.5 times higher than those of SnO2, SnS2, and physical mixed samples, respectively. The experimental and theoretical calculation results reveal that the charge transfer mechanism of SnO2/SnS2 conforms to S-scheme heterojunction. With the help of built-in electric field, band bending, and Coulomb gravity, SnO2/SnS2 S-scheme heterojunction has high redox ability and strong separation efficiency of photogenerated carriers. This work provides a new approach for in-situ preparation of novel S-scheme SnO2/SnS2 heterojunction photocatalysts for environmental remediation.
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