Co‐Monomer Control of Carbon Nitride Semiconductors to Optimize Hydrogen Evolution with Visible Light

Bottom–up synthesis of graphitic carbon nitride semiconductor catalysts for the photocatalytic evolution of hydrogen by visible light is achieved through the polymerization of dicyandiamide with organic monomers bearing cyano groups, amino groups, or both. This strategy allows ample opportunity to adjust the physical and chemical properties of the resulting heterogeneous carbon-nitride-based organocatalysts. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.