化学
二苯基膦
艾伦
碳原子
激进的
药物化学
有机化学
磷化氢
催化作用
戒指(化学)
作者
Terence N. Mitchell,Kerstin Heesche
标识
DOI:10.1016/0022-328x(91)86141-c
摘要
Diphenylphosphine adds readily to alkynes and allenes under free radical conditions. Alkynes normally give E-vinylphosphines as the primary (kinetic) product, but Z-vinylphosphines are the main products isolated. Allenes generally give complex product mixtures in which the predominant components are vinyl phosphines formed via addition of the Ph2P. radical to the central carbon atom of the allene fragment.
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