过电位
纳米片
催化作用
镍
析氧
分解水
硫化
化学工程
材料科学
纳米技术
化学
冶金
电化学
有机化学
电极
工程类
光催化
物理化学
作者
Pan Guo,Yuxuan Wu,Woon‐Ming Lau,Hao Liu,Limin Liu
标识
DOI:10.1016/j.jallcom.2017.06.299
摘要
Hydrogen is the most promising alternative energy source for many common applications because its combustion product is only water and it has a very high calorific-value. However, the overpotential in water-splitting is high due to the harsh oxygen evolution reaction (OER). Therefore, effective catalysts which are low-cost and easy to prepare are urgently needed to stimulate the reaction. Herein we constructed 3D CoS nanosheets arrays on nickel foam through a combination of electrodeposition and sulfidation. The as-prepared catalyst can catalyze OER efficiently with an overpotential of 297 mV to generate 10 mA cm−2 current density in 1 M KOH and is able to maintain excellent performance over 40 h without obvious degradation.
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