材料科学
阴极
法拉第效率
退火(玻璃)
电化学
兴奋剂
阳极
原子层沉积
化学工程
石墨烯
氧化物
离子
纳米技术
图层(电子)
复合材料
冶金
光电子学
电极
化学
物理化学
有机化学
工程类
作者
Yanan Hou,Xifei Li,Wen Liu,Huari Kou,Hirbod Maleki Kheimeh Sari,Xiaosheng Song,Jianwei Li,Shuming Dou,Xiaojing Liu,Sixu Deng,Dejun Li,Xueliang Sun
标识
DOI:10.1016/j.mtener.2019.100353
摘要
The structural instability and sluggish kinetic process of the pristine Na0.75Ni0.2Co0.2Mn0.6O2 (NCM) occurring at a high working voltage result in obvious capacity loss. In this study, Fe3+ doping onto the surface of the P2-type Na0.75Ni0.2Co0.2Mn0.6O2 (NCM) was fulfilled via post-annealing atomic layer deposition (ALD) derived Fe2O3 layer. It indicates that the modified NCM cathode materials exhibit better crystal structure stability and electrochemical behavior than the pristine NCM at wide voltage windows of 2.4–4.5 V and 2.4–4.7 V vs. Na/Na+. Furthermore, the ALD-30C-annealing material shows a higher initial capacity of 107 mA h g−1 at 0.1C (20 mA g−1), and it can reach a reversible capacity of 78 mA h g−1 and Coulombic efficiency of 96.6% after 100 cycles at the cutoff voltage of 4.5 V. Amazingly, combined with reduced graphene oxide (rGO) as an anode material, the ALD-30C-annealing cathode material exhibits notable full cell performance with the specific energy density of 160 Wh kg−1 at the high voltage widows of 2.4–4.5 V after 100 cycles. The designed strategy in this work may be one of the most promising perspectives toward the high performance cathode materials for SIBs.
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