极化(电化学)
统计物理学
理论物理学
物理
连续统假说
电介质
模型论
边值问题
德鲁德模型
经典力学
数学
量子力学
化学
物理化学
离散数学
作者
Ralf Blossey,Rudolf Podgornik
标识
DOI:10.1088/1751-8121/acb40c
摘要
Abstract We develop a comprehensive continuum model capable of treating both electrostatic and structural interactions in liquid dielectrics. Starting from a two-order parameter description in terms of charge density and polarization, we derive a field-theoretic model generalizing previous theories. Our theory explicitly includes electrostatic and structural interactions in the bulk of the liquid and allows for polarization charges within a Drude model. In particular we provide a detailed description of the boundary conditions which include the charge regulation mechanism and surface polarization, which is explained both in general terms and analyzed for an exemplary model case. Future applications of our theory to predict and validate experimental results are outlined.
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