A Review of Smart Superwetting Surfaces Based on Shape‐Memory Micro/Nanostructures

Abstract Bioinspired smart superwetting surfaces with special wettability have aroused great attention from fundamental research to technological applications including self‐cleaning, oil–water separation, anti‐icing/corrosion/fogging, drag reduction, cell engineering, liquid manipulation, and so on. However, most of the reported smart superwetting surfaces switch their wettability by reversibly changing surface chemistry rather than surface microstructure. Compared with surface chemistry, the regulation of surface microstructure is more difficult and can bring novel functions to the surfaces. As a kind of stimulus‐responsive material, shape‐memory polymer (SMP) has become an excellent candidate for preparing smart superwetting surfaces owing to its unique shape transformation property. This review systematically summarizes the recent progress of smart superwetting SMP surfaces including fabrication methods, smart superwetting phenomena, and related application fields. The smart superwettabilities, such as superhydrophobicity/superomniphobicity with tunable adhesion, reversible switching between superhydrophobicity and superhydrophilicity, switchable isotropic/anisotropic wetting, slippery surface with tunable wettability, and underwater superaerophobicity/superoleophobicity with tunable adhesion, can be obtained on SMP micro/nanostructures by regulating the surface morphology. Finally, the challenges and future prospects of smart superwetting SMP surfaces are discussed.