膜
纳滤
共价有机骨架
共价键
化学工程
单体
堆积
成核
材料科学
高分子化学
化学
有机化学
聚合物
生物化学
工程类
作者
Fan Yang,Jing Guo,Chengzhe Han,Junhui Huang,Zhiwei Zhou,Shi‐Peng Sun,Yanqiu Zhang,Lu Shao
出处
期刊:Science Advances
[American Association for the Advancement of Science (AAAS)]
日期:2024-12-11
卷期号:10 (50)
标识
DOI:10.1126/sciadv.adr9260
摘要
Although covalent organic frameworks (COFs) demonstrate notable potential for developing advanced separation membranes, contemporary COF membranes still lack controlled stacking and highly efficient sieving. Here, Turing-architecture COF membranes were constructed by engineering a reaction-diffusion assembly process via heterogeneous nucleation synthesis with tannic acid (TA). TA covalently binds with amine monomers to form a composite precursor with increased reactivity and decreased diffusivity. This altered the pathway of Schiff base reactions with aldehyde monomers, fulfilling suitable reaction-diffusion conditions, and ultimately formed the labyrinthine stripe or spot-patterned Turing COF film with controlled stacking and uniform pore structure. This endows our COF membrane with highly efficient molecule sieving ability for organic solvent nanofiltration while exhibiting a flux that is 621% greater than that of commercial membranes. Thus, this study provides a paradigm for the in situ synthesis of highly efficient COF membranes for diversely sustainable separations.
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