Towards ductile and high barrier poly(L-lactic acid) ultra-thin packaging film by regulating chain structures for efficient preservation of cherry tomatoes

The irreconcilable paradox between barrier performance and ductility is a "stumbling block" restricting the development of poly(L-lactic acid) (PLLA) films in the packaging industry. In this work, we reported the fabrication of an ultra-thin PLLA-based film with barrier properties and ductility by adjusting the polarity and conformational behavior of the polymer chains. Firstly, a novel unsaturated poly(L-lactic acid-co-butyrate itaconate) P(LA-BI) copolymer containing CC double bonds was synthesized using melt polycondensation. The results reveal that the addition of 60 % of P(LA-BI) enables PLLA film to achieve an elongation at a break of 83.6 % due to P(LA-BI) containing partially branched structures, which resulted in the polymer chains being arranged more in a high-energy gg conformer. Meanwhile, because of the large number of CO polar groups in P(LA-BI), PLLA/P(LA-BI)