芳烯
聚合物
热稳定性
膜
材料科学
高分子化学
乙醚
缩聚物
化学工程
化学
有机化学
复合材料
烷基
芳基
工程类
生物化学
作者
Arijit Ghorai,Susanta Banerjee
标识
DOI:10.1016/j.progpolymsci.2023.101646
摘要
Phosphorus-containing polymers have gained special attention during the past several years as a result of their fascinating properties and wide-ranging applications. The various stable bonding configurations of phosphorus atoms have enabled the synthesis of a large number of stable monomers and polymers with unique and interesting properties, such as improved organo-solubility, good thermal stability, mechanical robustness, and excellent transport characteristics. This in-depth review aims to give an overview of the synthesis and structural modification of various phosphorus-containing polymers and their uses in different membrane-based applications. In the last decade, phosphorus-containing polymers such as polyimide, poly(arylene ether), poly(arylene thioether), poly(arylene ether sulfone), poly(phthalazinone ether), and polytriazole have been used as proton exchange membranes. Subsequently, these phosphorus-based polymers also emerged as an attractive class of polymers for proton exchange membranes due to the outstanding water retention capacity within the membranes as well as well-networked ionic channels for proton conduction, adhesive strength, and peroxide resistance. The incorporation of phosphorus atoms in polymeric materials has also emerged as one of the most effective methods for enhancing the refractive index of polymers. As a result, a large number of research works have been carried out on phosphorus-containing polymers for optical applications. In addition, phosphorus-based polymers have attracted interest in areas such as gas separation and flame retardance. Motivated by these recent developments, this article reviews the synthesis, classification, and structure-property-performance relationships of phosphorus-containing polymers and delineates recent advances in their application in areas such as proton exchange membranes, optoelectronics as well as gas separation applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI