Spatial and species-specific responses of biogenic volatile organic compound (BVOC) emissions to elevated ozone from 2014–2020 in China

环境科学 臭氧 挥发性有机化合物 中国 环境化学 大气科学 化学 气象学 地理 生态学 生物 考古 地质学
作者
Lingyu Li,Jing Cao,Yufang Hao
出处
期刊:Science of The Total Environment [Elsevier BV]
卷期号:868: 161636-161636 被引量:15
标识
DOI:10.1016/j.scitotenv.2023.161636
摘要

China suffered from serious and elevated ozone (O3) pollution during 2014–2020. O3 exposure increased with W126, a biologically based cumulative exposure index, at a rate of 1.738 ppm-hr yr−1. MEGAN3.1 was applied to estimate biogenic volatile organic compound (BVOC) emissions and their response to O3 pollution in China by quantifying species responses to O3 stress. In 2020, China's BVOC emissions were 23.26 Tg when considering the effects of O3 pollution, which was 1.7 % higher than that without O3 stress. Isoprene, monoterpenes, sesquiterpenes, and other VOC emissions changed by −1.0 %, 1.4 %, 15.5 %, and 2.7 %, respectively. The stimulated BVOC emissions were mainly focused on the North China Plain (NCP) and a partial area of the Tibetan Plateau, which increased by >45 %. Changes in monthly emissions differed, with the greatest increase, 181 tons (3.25 %), in August. The seasonal patterns for the impacts of O3 pollution were also distinguished spatially. The elevated O3 exposure caused BVOC emission increases of 104.7 Gg yr−1 during 2014–2020, with isoprene, monoterpenes, sesquiterpenes, and other VOCs contributing −18.6 %, 27.5 %, 40.4 %, and 50.8 %, respectively. The greatest increase in emissions appeared on the NCP and eastern and central China, with annual increases of >100 tons per grid (36 km × 36 km). The interannual variations in BVOC emissions also displayed different seasonal patterns.
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