Cellulose nanofiber powered interface engineering strategy to manufacture mechanically stable, moldable, recyclable, and biodegradable cellulose foam

纤维素 纳米纤维 材料科学 复合材料 化学工程 高分子科学 工程类
作者
Longfei Sun,Jing Lü,Xinxin Chen,Hanfei Zhao,Lin Liu,Juming Yao
出处
期刊:Chemical Engineering Journal [Elsevier BV]
卷期号:498: 155155-155155
标识
DOI:10.1016/j.cej.2024.155155
摘要

In this work, an ingenious and energy-efficient interface engineering strategy is developed to manufacture pulp cellulose foam via incorporating cellulose nanofiber/alkyl ketene dimer (CNF/AKD) Pickering emulsions. In this strategy, CNF/AKD emulsion can uniformly anchor onto pulp microfiber surface, not only achieving interfacial exoskeleton reinforcement, but also enabling low energy surface, which facilitates the direct and large-scale production of lightweight pulp/CNF/AKD (PCA) foam by oven drying without requiring any harmful crosslinking chemistries. By simply regulating the mass fractions of CNF and AKD in emulsion, the prepared PCA foams can achieve excellent and tunable 3D porous structure, mechanical performance, water resistance and wet stability. The dry compressive modulus and wet compressive modulus underwater of PCA foams with low density of 0.09 g/cm3 can reach 0.67 and 0.57 MPa, respectively. Even 1 week in water, the compressive modulus still retains 76.2 % of initial modulus. Notably, the proposed interface engineering strategy provides remarkable formability, moldability and structural designability, enabling cellulose foam to be customized into complex and delicate 3D macroscopic structures for different scenarios. Furthermore, the PCA foam displays economically feasible closed-loop recyclability by easy hot-water disintegration and natural biodegradability in soil. Therefore, this work proves a cost-effective and viable interface engineering strategy for scalable production of lightweight, mechanically stable, recyclable, biodegradable cellulose foams with high environmental benefits and low petrochemical consumption.
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