材料科学
微观结构
涂层
纳米晶材料
散裂
内氧化
冶金
晶界
溅射沉积
复合材料
溅射
合金
薄膜
纳米技术
量子力学
物理
中子
作者
Zongke Zhao,Jinlong Wang,Minghui Chen,Jianqiang Zhang,Fuhui Wang,David J. Young
出处
期刊:Acta Materialia
[Elsevier]
日期:2022-10-01
卷期号:239: 118264-118264
被引量:31
标识
DOI:10.1016/j.actamat.2022.118264
摘要
Two MCrAlY coatings with the same nominal composition but different microstructures are prepared by magnetron sputtering (MS) and arc ion plating (AIP). Their oxidation at 1000°C led to very different results. The relatively coarse grained AIP coating formed a duplex-layer scale, consisting of external θ-Al2O3 and internal α-Al2O3, with small amounts of NiCr2O4. Severe surface undulation was accompanied by the development of numerous cracks and voids. Aluminum depletion transformed the AIP coating from β to γ, causing volume shrinkage, promoting scale spallation and leading to premature failure. In contrast, the nanocrystalline MS coating was less degraded due to its columnar crystal structure and high-density of grain boundaries which provided rapid Al diffusion. Oxidation of this coating was characterized by a faster θ-Al2O3 to α-Al2O3 transformation and formation of an exclusive α-Al2O3 scale, protecting the surface.
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