三硫化二甲酯
化学
二甲基硫醚
风味
美拉德反应
过氧化氢
二甲基二硫化物
有机化学
葡萄糖酸
硫化氢
甲硫醇
硫黄
硫化物
己醛
葡萄糖氧化酶
过氧化物
食品科学
酶
作者
Dongsheng Luo,Xinxing Xu,Shuping Bi,Yuping Liu,Jihong Wu
标识
DOI:10.1021/acs.jafc.9b03398
摘要
This research applied inhibitors to reduce the content of cooked off-flavor components (dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide, and 3-(methylthio)propanaldehyde) in heat-treated melon juice. The effects of glucose oxidase (GOD) on the formation and release of these four volatile sulfur compounds were also investigated. Results showed that GOD strongly inhibited the formation of the four compounds. In GOD-treated melon juice, S-methylmethionine was strongly protonated and not easily degraded into dimethyl sulfide. Moreover, the release of the dimethyl sulfide that did form was restrained by the hydrophobic interactions of gluconic acid and oxidation by hydrogen peroxide. In addition, gluconic acid (or glucose) and hydrogen peroxide could form a stable complex with methionine in an acidic matrix and thus prevented the methionine from producing 3-(methylthio)propanaldehyde, dimethyl disulfide, and dimethyl trisulfide by the Maillard reaction during heat processing.
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