清晨好,您是今天最早来到科研通的研友!由于当前在线用户较少,发布求助请尽量完整地填写文献信息,科研通机器人24小时在线,伴您科研之路漫漫前行!

Ceramic coatings for small modular reactors

材料科学 因科镍合金625 涂层 陶瓷 腐蚀 冶金 镍铬合金 因科镍合金 往复运动 冷却液 复合材料 合金 机械工程 工程类 气体压缩机
作者
Edward H. Williamson
标识
DOI:10.15126/thesis.00853296
摘要

In the nuclear sector, ceramic coatings can be applied to reactor components such as bearings and bolts to improve durability. Historically, electrodeposited hard chromium plate (HCP) has been used to provide wear and corrosion resistance in reactor environments. As a result of regulation changes and adverse health effects associated with Cr(VI), the use of HCP will soon be heavily restricted. Therefore, candidate ceramic materials have been identified which could match or improve upon the performance of HCP as the Rolls-Royce small modular reactor is developed. After a detailed materials selection process, ceramic coatings of Cr2O3, WC-(W,Cr)2C-Ni, Cr3C2-NiCr, CrN and CrAlN thermally sprayed or electron beam physical vapour deposited on to substrates of Inconel 625 were acquired. HCP, also deposited on Inconel 625, using electrodeposition was obtained for comparison. Tests to emulate nuclear reactor conditions including irradiation, corrosion and sliding wear were devised and undertaken to provide an initial screening programme for the candidate materials. A preliminary study into the irradiation performance used implanted ions, as surrogates for neutrons, with the HCP and Cr3C2-NiCr coatings showing no discernible damage in terms of peak shifts or broadening. Corrosion performance was also initially assessed, using a high temperature, high pressure autoclave, filled with simulated nuclear reactor coolant water. The Cr3C2-NiCr and CrN coatings were the least affected by this corrosive environment, as assessed by mass loss. The sliding wear performance of the coatings was examined in greater detail using an Inconel 625 ball undergoing reciprocating motion on a flat coating counterface under dry conditions, as well as in deionised water and simulated nuclear reactor coolant water environments, all at room temperature. Two wear rate analysis methods (mass loss and optical profilometry) were compared and were found to provide complementary information. Of the coatings, Cr2O3 was found to have the highest wear resistance, with no particle pull-out, likely due to its homogenous microstructure. Overall, the results from this initial screening programme indicated that the candidate coatings were unable to match the performance of HCP across all three testing regimes of irradiation, corrosion and wear. The Cr2O3 coating had the best overall performance in irradiation and wear testing but there were potential concerns over its resistance to pitting corrosion. The Cr3C2-NiCr coating was shown to offer comparable irradiation and corrosion performance to HCP and could be considered for use in applications where wear performance is not as critical. In addition to the outcomes for specific coatings, the study highlighted some key factors for further testing, such as the importance of using borated water in wear testing and the benefit of X-ray photon electron spectroscopy in providing additional information regarding wear mechanisms.

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
4秒前
瑁柏发布了新的文献求助10
9秒前
Siren发布了新的文献求助10
16秒前
59秒前
Ggap1发布了新的文献求助10
1分钟前
Ggap1完成签到,获得积分10
1分钟前
思源应助Siren采纳,获得10
1分钟前
Raul完成签到 ,获得积分10
1分钟前
Akim应助科研通管家采纳,获得10
1分钟前
Hello应助科研通管家采纳,获得10
1分钟前
1分钟前
1分钟前
Siren发布了新的文献求助10
1分钟前
Xu完成签到,获得积分20
1分钟前
荣浩宇完成签到 ,获得积分10
1分钟前
1分钟前
科研通AI5应助和谐乌龟采纳,获得10
2分钟前
2分钟前
2分钟前
mo发布了新的文献求助10
2分钟前
2分钟前
雪山飞龙完成签到,获得积分10
3分钟前
3分钟前
benzene完成签到 ,获得积分10
3分钟前
5433完成签到 ,获得积分10
3分钟前
KINGAZX完成签到 ,获得积分10
3分钟前
muriel完成签到,获得积分10
3分钟前
小马甲应助傲娇的夜山采纳,获得10
3分钟前
3分钟前
orixero应助Demi_Ming采纳,获得10
3分钟前
3分钟前
可爱的函函应助mo采纳,获得10
3分钟前
科研通AI2S应助雪白小丸子采纳,获得10
3分钟前
傲娇的夜山完成签到,获得积分10
3分钟前
mo完成签到,获得积分20
3分钟前
好天气完成签到 ,获得积分20
4分钟前
好天气关注了科研通微信公众号
4分钟前
领导范儿应助533采纳,获得10
4分钟前
4分钟前
Demi_Ming发布了新的文献求助10
4分钟前
高分求助中
A new approach to the extrapolation of accelerated life test data 1000
Cognitive Neuroscience: The Biology of the Mind 1000
Technical Brochure TB 814: LPIT applications in HV gas insulated switchgear 1000
Immigrant Incorporation in East Asian Democracies 600
Nucleophilic substitution in azasydnone-modified dinitroanisoles 500
不知道标题是什么 500
A Preliminary Study on Correlation Between Independent Components of Facial Thermal Images and Subjective Assessment of Chronic Stress 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3968504
求助须知:如何正确求助?哪些是违规求助? 3513331
关于积分的说明 11167297
捐赠科研通 3248697
什么是DOI,文献DOI怎么找? 1794417
邀请新用户注册赠送积分活动 875030
科研通“疑难数据库(出版商)”最低求助积分说明 804664