UV/TiO2 Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal

Antibiotics are the most common pharmaceutical compounds, and they have been extensively used for the prevention and treatment of bacterial diseases for more than 50 years. However, merely a small fraction of antibiotics is metabolized in the body, while the rest is discharged into the environment through excretion, which can cause potential ecological problems and human health risks. In this study, the elimination of seventeen antibiotics from real livestock wastewater effluents was investigated by UV/TiO2 advanced oxidation process. The effect of process parameters, such as TiO2 loadings, solution pHs, and antibiotic concentrations, on the efficiency of the UV/TiO2 process was assessed. The degradation efficiency was affected by the solution pH, and higher removal efficiency was observed at pH 5.8 and 9.9, while the catalyst loading had no significant effect on the degradation efficiency at these experimental conditions. UV photolysis showed a good removal efficiency of the antibiotics. However, the highest removal efficiency was shown by the UV/photocatalyst system due to their synergistic effects. The results showed that more than 90% of antibiotics were removed by UV/TiO2 system during the 60 min illumination, while the corresponding TOC and COD removal was only 10 and 13%, respectively. The results of the current study indicated that UV/TiO2 advanced oxidation process is a promising method for the elimination of various types of antibiotics from real livestock wastewater effluents.