Photo-mediated synthesis of 1,2-dideoxy-2-phosphinylated carbohydrates from glycals: the reduction of glycosyl radicals to glycosyl anions
糖基
化学
激进的
组合化学
有机化学
作者
Hai Li,Kai-Cheng Yu,Jiakun Su,Wei Ouyang,Nai-Li Fan,Xiang‐Guo Hu
出处
期刊:Green Chemistry [The Royal Society of Chemistry] 日期:2022-01-01卷期号:24 (21): 8280-8291被引量:8
标识
DOI:10.1039/d2gc01513g
摘要
A metal-free, photo-mediated method for the synthesis of C2-phosphorylated carbohydrates has been developed, whose reaction mechanism consists of the reduction of a glycosyl radical to a glycosyl anion.