柠檬黄
检出限
微分脉冲伏安法
色谱法
电化学
稀释
化学
明胶
材料科学
循环伏安法
电极
有机化学
热力学
物理
物理化学
作者
Guilherme Figueira Alves,Lucas V. de Faria,Thalles Pedrosa Lisboa,Cassiano Cunha de Souza,Bruno Luiz Mendes Fernandes,Maria Auxiliadora Costa Matos,Renato Camargo Matos
标识
DOI:10.1016/j.microc.2022.107799
摘要
Herein a simple method to fabricate an electrochemical paper-based analytical device using a cost-effective conductive ink based on graphite powder and nail polish, supported on cardboard is described for the simultaneous electrochemical determination of tartrazine (TZ) and sunset yellow (SY) by Differential Pulse Voltammetry (DPV). The electrochemical method was optimized and presented excellent analytical performance with low detection limits of 2.38 and 2.09 µmol/L for SY and TZ, respectively, a wide linear range from 4.0 to 60.0 µmol/L, and adequate precision (RSD less than 6.8 %). Furthermore, the proposed method did not require a complex sample treatment step (only simple dilution) and, it was applied in the determination of both colorants in samples of isotonic, juice, powdered juice, freeze pop, and gelatin, with satisfactory selectivity in relation to other food ingredients found in the analyzed samples. Thus, the disposable device demonstrated to be an excellent alternative tool for the analysis of both colorants in food samples.
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