Adsorption of Single and Mixed Surfactants onto Jordanian Natural Clay

Abstract The adsorption of sodium dodecyl sulfate (SDS) and N,N-dimethyldodecan-1-amine oxide (DDAO) and their mixtures from their solutions, onto Jordanian Natural Clay (JNC) was investigated at room temperature. The clay was firstly analyzed with X-ray fluorescence technique. The surface tension of the single and mixed surfactant solutions was then measured as a function of the total surfactant concentration and the critical micelle concentration ( CMC ) values of these solutions were determined. The interaction between SDS and DDAO as indicated by their interaction parameter was calculated according to the regular solution model. Adsorption of single surfactants onto 3 % wt/vol Jordanian Natural Clay, using the depletion method, was ultimately investigated. Although no absorbed SDS molecules were found onto the Jordanian Clay, but a pronounced adsorption tendency for DDAO and mixed SDS/DDAO molecules was obtained. The amounts of surfactant adsorbed onto 3 wt/vol% JNC follow the trend: SDS/DDAO > DDAO > SDS indicating the importance of synergistic interaction of surfactants on their adsorption behavior.