催化作用
等离子体
化学
扩散
八角石
无量纲量
活化能
非热等离子体
离子
化学物理
纳米技术
无机化学
物理化学
材料科学
热力学
沸石
有机化学
物理
量子力学
作者
Hyun‐Ha Kim,Yoshiyuki Teramoto,Nobuaki Negishi,Atsushi Ogata
标识
DOI:10.1016/j.cattod.2015.04.009
摘要
Low temperature catalytic reactions induced by nonthermal plasma (NTP) have been of great interest in plasma chemistry for application to pollution control and energy-related issues. Current progress in the experimental observations and the understanding of interactions between NTP and catalyst are reviewed herein. Considering the diffusion length and lifetime of reactive species, we introduced a dimensionless parameter Λ that describes the criteria for a direct interaction between NTP and catalysts. Several lines of experimental evidences on the interaction were introduced: discharge mode, formation of metal cluster ions, and plasma-induced fluorescence from the catalyst. For faujasite zeolites, the Si/Al ratio was found to be an important parameter that determines the propagation of surface streamers and catalytic performance. The oxidation status of metals is closely correlated with the Si/Al ratio, which is related to substantial changes in electrical resistivity.
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