催化作用
沸石咪唑盐骨架
双金属片
铂金
钴
咪唑酯
化学工程
材料科学
纳米颗粒
金属有机骨架
化学
无机化学
纳米技术
有机化学
吸附
工程类
作者
Lina Chong,Jianguo Wen,Joseph Kubal,Fatih G. Sen,Jianxin Zou,Jeffery P. Greeley,Maria K. Y. Chan,Heather M. Barkholtz,Wenjiang Ding,Di‐Jia Liu
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2018-11-08
卷期号:362 (6420): 1276-1281
被引量:843
标识
DOI:10.1126/science.aau0630
摘要
Combine and conquer Platinum (Pt)–group metals, which are scarce and expensive, are used for the demanding oxygen reduction reaction (ORR) in hydrogen fuel cells. One competing approach for reducing their use is to create nanoparticles with earth-abundant metals to increase their activity and surface area; another is to replace them with metals such as cobalt (Co) in carbide or nitride sites. Chong et al. thermally activated a Co metal-organic framework compound to create ORR-active Co sites and then grew PtCo alloy nanoparticles on this substrate. The resulting catalyst had high activity and durability, despite its relatively low Pt content. Science , this issue p. 1276
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