纳米棒
热液循环
循环伏安法
超级电容器
介电谱
材料科学
水热合成
化学工程
电化学
电极
比表面积
锰
纳米结构
纳米技术
化学
冶金
有机化学
工程类
物理化学
催化作用
作者
Xiao Bai,Xiaofeng Tong,Yanli Gao,Wanqing Zhu,Can Fu,Jingwen Ma,Tianci Tan,Chunlei Wang,Yongsong Luo,Haibin Sun
标识
DOI:10.1016/j.electacta.2018.06.003
摘要
Manganese dioxide (MnO2) is an ideal electrode material for supercapacitors due to its low cost and large theoretical specific capacity. We reported the hydrothermal synthesis MnO2 nanostructures with different morphologies through the variation of hydrothermal temperature and dwell time. It was found that cauliflower-like δ-MnO2 particles are prepared at a lower temperature while the needle-like α-MnO2 nanorods are formed at a higher temperature. The morphologies of MnO2 were also affected by the hydrothermal dwell time. The needle-like α-MnO2 nanorods have the higher specific surface (114 m2 g−1) than that of the cauliflower-like δ-MnO2 particles. Electrochemical properties were evaluated using cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD) and electrochemical impedance spectroscopy (EIS). The hierarchical multidimensional MnO2 architecture nanostructured surface with particles and nanorods, shows a maximum specific capacity (311.52 F g-1 at 0.3 A g−1). These results provided a generic guideline in developing different nanostructured electrode materials for electrochemical energy storage.
科研通智能强力驱动
Strongly Powered by AbleSci AI