Abstract This article describes a fast, efficient, economical, and environmentally friendly method for the preparation of a series of ferrocenyl‐substituted 1,5‐diketone compounds via Michael addition of ferrocenyl‐substituted chalcones with deoxybenzoin or dibenzyl ketone under solvent‐free conditions, and affords the corresponding Michael adducts with excellent yields of 77–93%. Keywords: Chalcone1,5‐diketoneferroceneMichael additionsolvent‐free condition Acknowledgments Financial assistance from the National Natural Science Foundation of China (Nos. 20172039 and 20472062) and Natural Science Foundation of Jiangsu Province (No. BK2004038) is acknowledged.