Pummer重排
亚砜
化学
硫酯
磺酰
有机化学
高分子化学
醋酸酐
催化作用
酶
烷基
作者
Liliana Marzorati,Eduardo K. C. Yoshikawa,Ataualpa Albert Carmo Braga,Cláudio Di Vitta
标识
DOI:10.1080/17415993.2013.853066
摘要
Sulfoxides bearing thioester and ester groups at the α position under heating at ca. 140°C undergo Pummerer thermal rearrangement. However, for sulfonyl sulfoxide, a complex mixture of products is formed. Plausible mechanism is advanced.
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