氢化酶
拉曼光谱
太赫兹辐射
红外线的
拉曼散射
红外光谱学
吸收(声学)
材料科学
化学
光化学
氢
物理化学
光电子学
光学
物理
有机化学
复合材料
作者
Christopher J. Stromberg,Casey L. Kohnhorst,Glenn A. Van Meter,Elizabeth A. Rakowski,Benjamin W. Caplins,Tiffany A. Gutowski,Jennifer Mehalko,Edwin J. Heilweil
标识
DOI:10.1016/j.vibspec.2011.02.012
摘要
Abstract Using Raman, terahertz (THz), and mid-infrared (IR) spectroscopies, the vibrational spectra of two chromophore models of hydrogen-producing [FeFe]-hydrogenase, Fe 2 (μ-S 2 C 3 H 6 )(CO) 6 and Fe 2 (μ-S 2 C 2 H 4 )(CO) 6 , have been assigned. The combination of absorption and scattering techniques, along with DFT calculations, allows for assignments to be made without traditional isotopic substitution methods.
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