吸附
纳米孔
一氧化碳
选择性
化学
铜
分子
离子
化学工程
Crystal(编程语言)
二氧化碳
碳纤维
材料科学
纳米技术
吸附
有机化学
催化作用
计算机科学
程序设计语言
复合材料
工程类
复合数
作者
Hiroshi Satō,Wataru Kosaka,Ryotaro Matsuda,Akihiro Hori,Yuh Hijikata,Rodion V. Belosludov,Shigeyoshi Sakaki,Masaki Takata,Susumu Kitagawa
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2013-12-13
卷期号:343 (6167): 167-170
被引量:488
标识
DOI:10.1126/science.1246423
摘要
Soft, Selective CO Sorption Many industrial processes produce CO, which could be used as a chemical feedstock, but separation of CO from other gases, especially N 2 , is too difficult to be economically viable. Sato et al. (p. 167 , published online 12 December 2013) now report that a porous coordination polymer containing Cu 2+ ions can selectivity bind CO through serial structural changes reminiscent of allosteric effects in proteins. The separation of CO-N 2 mixtures can be achieved with a low input energy for CO desorption.
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