倍半萜
烯丙基重排
柏树
洋甘菊
化学
有机化学
植物
生物
催化作用
作者
Koon‐Sin Ngo,Geoffrey D. Brown
出处
期刊:Perkin 1
日期:2000-01-01
卷期号: (2): 189-194
被引量:7
摘要
Five muurolane (1–5), one nor-seco-muurolane (6) and one nor-muurolane (7) sesquiterpene natural products recently reported from Cupressus bakeri have been obtained by chemical synthesis together with the unnatural 7-epimeric amorphane analogues of four of these sesquiterpenes (15, 16, 18 and 19). The conversion of sesquiterpene allylic tertiary alcohols 1, 2, 15 and 16 into regioisomeric sesquiterpene dienes 3–5 and 17–20 was investigated in vitro by NMR and the mechanism for such dehydrations and their relevance to the origins of sesquiterpene dienes which have been reported as natural products (such as 3–5) is discussed.
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