锂(药物)
电解质
磺酸盐
甲基丙烯酸酯
离子电导率
电化学
离子
材料科学
热稳定性
聚合物
化学
无机化学
化学工程
高分子化学
钠
有机化学
复合材料
共聚物
电极
医学
冶金
物理化学
内分泌学
工程类
作者
Panying Ji,Jun Fang,Yiyong Zhou,Peng Zhang,Chao Li
标识
DOI:10.1002/celc.201700256
摘要
Abstract A new type of single‐ion conducting polymer electrolyte for lithium‐ion batteries, poly(hexafluorobutyl methacrylate‐ co ‐lithium allyl sulfonate) (P (HFMA‐ co ‐ASLi)), was firstly prepared by copolymerizing hexafluorobutyl methacrylate (HFMA) and sodium allyl sulfonate (SAS) with a subsequent lithiation process. The prepared polymer electrolyte exhibits high lithium ionic conductivity (10 −4 S cm −1 at 80 °C) and excellent cycle performance at high temperature, which could be attributed to the good thermal stability (remains stable up to 300 °C), mechanical properties (7.1 MPa for breaking strength) and high lithium‐ion transference number (0.92). The electrolyte also displays good electrochemical stability (4.6 V). Our obtained results prove that the polymer P (HFMA‐ co ‐ASLi) is a promising candidate electrolyte for lithium‐ion batteries.
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