材料科学
超级电容器
堆积
电极
石墨烯
假电容器
纳米复合材料
电化学
纳米技术
核磁共振
物理
物理化学
化学
作者
Weihong Liu,Zhiqiang Wang,Yanli Su,Qingwen Li,Zhigang Zhao,Fengxia Geng
标识
DOI:10.1002/aenm.201602834
摘要
Abstract 2D nanostructures with high surface area and flexibility are regarded as a promising building platform for flexible supercapacitors that are attracting tremendous attention due to their potential applications in various wearable technologies. Notably, although pseudocapacitive metal oxides are widely accepted as a very important class of electrochemically active materials, the utilization of 2D metal oxide sheets in the preparation of flexible supercapacitors is very rare. The scarcity of a suitable filler with the integrated properties of both high conductivity and excellent hydrophilicity is probably to blame. In this work, by introducing a recently discovered intriguing material, Ti 3 C 2 sheets, a novel MnO 2 /Ti 3 C 2 hybrid with a molecularly stacked structure is developed using a simple and scalable mixing and filtration method. Their individual advantages are combined in the hybrid, thus delivering excellent electrochemical performances. A highly flexible and symmetric supercapacitor based on the novel hybrid electrode manifests top‐class electrochemical performance with maximum energy and power densities of 8.3 W h kg −1 (at 221.33 W kg −1 ) and 2376 W kg −1 (at 3.3 W h kg −1 ), respectively, regardless of the various bending states, suggesting enormous possibilities for applications in future flexible and portable micropower systems.
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