Co‐Construction of Sulfur Vacancies and Heterojunctions in Tungsten Disulfide to Induce Fast Electronic/Ionic Diffusion Kinetics for Sodium‐Ion Batteries

Abstract Engineering novel electrode materials with unique architectures has a significant impact on tuning the structural/electrochemical properties for boosting the performance of secondary battery systems. Herein, starting from well‐organized WS 2 nanorods, an ingenious design of a one‐step method is proposed to prepare a bimetallic sulfide composite with a coaxial carbon coating layer, simply enabled by ZIF‐8 introduction. Rich sulfur vacancies and WS 2 /ZnS heterojunctions can be simultaneously developed, that significantly improve ionic and electronic diffusion kinetics. In addition, a homogeneous carbon protective layer around the surface of the composite guarantees an outstanding structural stability, a reversible capacity of 170.8 mAh g −1 after 5000 cycles at a high rate of 5 A g −1 . A great potential in practical application is also exhibited, where a full cell based on the WS 2− x /ZnS@C anode and the P2‐Na 2/3 Ni 1/3 Mn 1/3 O 2 cathode can maintain a reversible capacity of 89.4 mAh g −1 after 500 cycles at 1 A g −1 . Moreover, the underlying electrochemical Na storage mechanisms are illustrated in detail by theoretical calculations, electrochemical kinetic analysis, and operando X‐ray diffraction characterization.