材料科学
聚乙烯
聚酰胺
渗透
复合材料
结晶
热塑性塑料
极限抗拉强度
化学工程
化学
膜
生物化学
工程类
作者
Simon Backens,Jan Siering,Stefan Schmidt,Nikolai Glück,Wilko Flügge
出处
期刊:MP MATERIALPRUEFUNG - MP MATERIALS TESTING
[De Gruyter]
日期:2021-04-01
卷期号:63 (4): 311-316
被引量:7
摘要
Abstract Lightweight pressure vessels of type IV for hydrogen storage consist of a thermoplastic inner liner, commonly from polyethylene or polyamide. The liner is the permeation barrier against the compressed gas and must prevent the formation of cracks, also after temperature changes, for example after refueling processes. In the present work high-density polyethylene, cross-linked polyethylene, polyamide 6 and polyamide 12 were characterized by tensile tests, single notch impact tests and permeations measurements before and after a cyclic thermal aging process. The aging only lead to slight changes of mechanical properties due to post-crystallization, but to a significant decrease of permeation properties. This decrease was contributed to weakened, amorphous regions where chain splitting occurred. Considerable differences in properties resulted from different peroxide cross-linking times of polyethylene at the same temperature. A longer holding time at 200 °C led to an improvement in impact strength by a factor of more than three. However, the permeation properties decreased by about 50 %, indicating that peroxide cross-linking in the melt inhibited the formation of crystalline regions.
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