镓
材料科学
溶解
液态金属
碳纤维
化学工程
能量转换
高效能源利用
工艺工程
纳米技术
废物管理
冶金
复合材料
复合数
电气工程
物理
工程类
热力学
作者
Junma Tang,Jianbo Tang,Mohannad Mayyas,Danyang Wang,Jing Sun,Md. Arifur Rahim,Jiong Yang,Jialuo Han,Douglas J. Lawes,Rouhollah Jalili,Torben Daeneke,Maricruz G. Saborío,Zhenbang Cao,Claudia A. Echeverria,Francois‐Marie Allioux,Ali Zavabeti,Jessica L. Hamilton,Valerie D. Mitchell,Anthony P. O’Mullane,Richard B. Kaner,Dorna Esrafilzadeh,Michael D. Dickey,Kourosh Kalantar‐zadeh
标识
DOI:10.1002/adma.202105789
摘要
A green carbon capture and conversion technology offering scalability and economic viability for mitigating CO2 emissions is reported. The technology uses suspensions of gallium liquid metal to reduce CO2 into carbonaceous solid products and O2 at near room temperature. The nonpolar nature of the liquid gallium interface allows the solid products to instantaneously exfoliate, hence keeping active sites accessible. The solid co-contributor of silver-gallium rods ensures a cyclic sustainable process. The overall process relies on mechanical energy as the input, which drives nano-dimensional triboelectrochemical reactions. When a gallium/silver fluoride mix at 7:1 mass ratio is employed to create the reaction material, 92% efficiency is obtained at a remarkably low input energy of 230 kWh (excluding the energy used for dissolving CO2 ) for the capture and conversion of a tonne of CO2 . This green technology presents an economical solution for CO2 emissions.
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