材料科学
碳纳米纤维
双金属片
选择性
检出限
电化学
沸石咪唑盐骨架
电解质
咪唑酯
复合数
制作
电催化剂
化学工程
电化学气体传感器
纳米纤维
再现性
纳米技术
电极
碳纳米管
复合材料
色谱法
吸附
催化作用
有机化学
冶金
化学
物理化学
病理
金属有机骨架
工程类
医学
替代医学
金属
作者
Jiaxin Lin,Huan Lü,Yingchun Duan,Chenhong Yu,Li Li,Yaping Ding
标识
DOI:10.1007/s10853-021-06766-5
摘要
The detection method with potential ability to diagnose drugs in human serum rapidly, highly sensitivity and selectivity is of vital importance for clinical diagnosis. In this paper, an electrochemical sensor on the basis of composite material modified by zeolitic imidazolate framework (ZIF) on carbon nanofiber (CNF) surface is constructed, which is used for ultra-sensitive determination of adrenaline (AD). CoMnZIF-CNF combines the good conductivity of carbon nanofibers and the high electrocatalysis of CoMnZIF, which can improve the reaction activity and the sensing effect of adrenaline. The proposed sensor shows a good linear relationship between AD concentration from 5 to 1000 μM, and the detection limit is 0.22 μM. Meanwhile, CoMnZIF-CNF demonstrated the remarkable selectivity, significant repeatability and stability, as well as excellent reproducibility. Besides, through the analysis of AD in serum electrolyte, the practicability of the sensor was evaluated and the recovery rate was between 97.51 and 102.53%. On the basis of the results, the prepared sensor has a vital application prospect in detecting AD in actual sample analysis.
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