Molecule‐Based Ferroelectric Thin Films: Mononuclear Lanthanide Enantiomers Displaying Room‐Temperature Ferroelectric and Dielectric Properties

Angewandte ChemieVolume 119, Issue 36 p. 6944-6947 Zuschrift Molecule-Based Ferroelectric Thin Films: Mononuclear Lanthanide Enantiomers Displaying Room-Temperature Ferroelectric and Dielectric Properties† Xi-Li Li, Xi-Li Li State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorKai Chen Dr., Kai Chen Dr. Solid State Microstruct Lab, Department of Physics, Nanjing University, Hankou 22, Nanjing 210093, ChinaSearch for more papers by this authorYu Liu Prof. Dr., Yu Liu Prof. Dr. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun 130012, ChinaSearch for more papers by this authorZhao-Xi Wang, Zhao-Xi Wang State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorTian-Wei Wang, Tian-Wei Wang State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorJing-Lin Zuo Prof. Dr., Jing-Lin Zuo Prof. Dr. State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorYi-Zhi Li Prof. Dr., Yi-Zhi Li Prof. Dr. State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorYue Wang Prof. Dr., Yue Wang Prof. Dr. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun 130012, ChinaSearch for more papers by this authorJin Song Zhu Prof. Dr., Jin Song Zhu Prof. Dr. Solid State Microstruct Lab, Department of Physics, Nanjing University, Hankou 22, Nanjing 210093, ChinaSearch for more papers by this authorJun-Min Liu Prof. Dr., Jun-Min Liu Prof. Dr. Solid State Microstruct Lab, Department of Physics, Nanjing University, Hankou 22, Nanjing 210093, ChinaSearch for more papers by this authorYou Song Prof. Dr., You Song Prof. Dr. [email protected] State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorXiao-Zeng You Prof., Xiao-Zeng You Prof. [email protected] State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this author Xi-Li Li, Xi-Li Li State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorKai Chen Dr., Kai Chen Dr. Solid State Microstruct Lab, Department of Physics, Nanjing University, Hankou 22, Nanjing 210093, ChinaSearch for more papers by this authorYu Liu Prof. Dr., Yu Liu Prof. Dr. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun 130012, ChinaSearch for more papers by this authorZhao-Xi Wang, Zhao-Xi Wang State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorTian-Wei Wang, Tian-Wei Wang State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorJing-Lin Zuo Prof. Dr., Jing-Lin Zuo Prof. Dr. State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorYi-Zhi Li Prof. Dr., Yi-Zhi Li Prof. Dr. State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorYue Wang Prof. Dr., Yue Wang Prof. Dr. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun 130012, ChinaSearch for more papers by this authorJin Song Zhu Prof. Dr., Jin Song Zhu Prof. Dr. Solid State Microstruct Lab, Department of Physics, Nanjing University, Hankou 22, Nanjing 210093, ChinaSearch for more papers by this authorJun-Min Liu Prof. Dr., Jun-Min Liu Prof. Dr. Solid State Microstruct Lab, Department of Physics, Nanjing University, Hankou 22, Nanjing 210093, ChinaSearch for more papers by this authorYou Song Prof. Dr., You Song Prof. Dr. [email protected] State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this authorXiao-Zeng You Prof., Xiao-Zeng You Prof. [email protected] State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou 22, Nanjing 210093, China, Fax: (+86) 25-8331-4502Search for more papers by this author First published: 04 September 2007 https://doi.org/10.1002/ange.200701802Citations: 13 † This research was funded by the Major State Basic Research Development Program (grant nos. 2007CB925102, 2006CB806104, and 2006CB921800) and the National Natural Science Foundation of China (project no. 20531040). Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Beide Enantiomere des einkernigen Europium-Neutralkomplexes [Eu(tta)3L] wurden hergestellt (tta=2-Thenoyltrifluoracetonat; L=(−)- oder (+)-4,5- Pinenbipyridin für 1 bzw. 2). Messungen zum ferroelektrischen Verhalten dünner Filme von 1 und 2 ergaben E-P-Hystereseschleifen bei Raumtemperatur (Tc=28.0 °C) mit einer Restpolarisation von 0.022 μC cm−2 und einem Koerzitivfeld von 25 kV cm−1. Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z701802_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aT. Okubo, R. Kawajiri, T. Mitani, T. Shimoda, J. Am. Chem. Soc. 2005, 127, 17598–17599; 10.1021/ja056030p CASPubMedWeb of Science®Google Scholar 1bS. Horiuch, R. J. Kumai, Y. Tokuar, J. Am. Chem. Soc. 2005, 127, 5010–5011; 10.1021/ja042212s CASPubMedWeb of Science®Google Scholar 1cH. Irie, H. Saito, S. Ohkoshi, K. Hashimoto, Adv. Mater. 2005, 17, 491–494; 10.1002/adma.200400957 CASWeb of Science®Google Scholar 1dA. Sheikholeslami, Proc. IEEE 2000, 88, 667–689; 10.1109/5.849164 Web of Science®Google Scholar 1eC. A-Paz de Araujo, J. D. Cuchiaro, L. D. Macmillan, M. C. 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